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Mitsui, Hiroshi; Shimizu, Yuichi
Japan Atomic Energy Research Inst., Tokyo1978
Japan Atomic Energy Research Inst., Tokyo1978
AbstractAbstract
[en] A mixture of hydrogen (H2) and carbon dioxide (CO2) was irradiated with γ-rays from a cobalt-60 source. The molar ratio of H2 to CO2 was 4.0, the pressure of the mixture 9.0 kg/cm2 gauge at 300C, the temperature 500 - 4500C, the dose rate 8.34 x 105 rad/hr, and the total dose 20 Mrad. Carbon monoxide (CO), methane (CH4), and ethane (C2H6) were observable as the main products. The G-values for formations of CO, CH4, and C2H6 were 0.24, 0.25, and 0.03 at 1000C, and increased to 27.7, 2.1, and 1.9 at 4500C, respectively. The G-values were calculated from the yields after subtracting the yields due to the pure thermal reactions from the ones of the reactions under γ-irradiation. The activation energies of the G-values were 4.8, 0.0, and 0.0 kcal/mol below 2000C, and 11.3, 6.7, and 15.7 kcal/mol above 2500C for formations of CO, CH4, and C2H6, respectively. The boundary temperatures at which the activation energies changed were estimated to be 240, 221, and 2390C for the respective products. On the basis of these results, the temperature dependence of the radiation effect in the reaction of H2 with CO2 is discussed. (author)
Source
Dec 1978; 35 p
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