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Cheung, H.; Fuller, M.E.; Gaffney, E.S.
California Univ., Livermore (USA). Lawrence Livermore Lab1979
California Univ., Livermore (USA). Lawrence Livermore Lab1979
AbstractAbstract
[en] Four different models of the migration process have been reviewed to determine their suitability as a working model. While there are several common factors in the models additional factors are included to account for several possible effects. The detail of each model leads to a certain degree of difficulty in applying the model to the problem at hand. One model predicts that inclusions smaller than 0.1 mm dimension probably will not migrate. The other models do not consider size as a factor. Thermal diffusion (Soret effect) is considered insignificant in three models, while in the fourth model it is added to the concentration diffusion term. The following conclusions are made: (1) Temperature is the most significant parameter in all models and must be known as a function of time, and distance from the canister. (2) All four models predict about the same migration velocity for a given set of conditions. For 1000C and 10C/cm thermal gradient, the individual values are 3.0, 4.8, 5.6 and 6.4 mm/y. (3) The diffusion of ions through the brine inclusions is the rate controlling mechanism. (4) The difference between the thermal gradients in the liquid and in the solid should always be considered, and is a function of droplet shape. (5) The model based upon work by Nernst is easiest to use since all necessary parameters are readily available in the literature. However, of the four models is predicts the lowest migration rate. (6) The maximum volume of pure brine accumulated at the canister surface would be less than 20-40 liters in 50 years, for a canister initial thermal power of 3.5 kW. Bitterns would migrate proportionately less volume. A compuber code, BRINE, was developed to make these calculations by means of any of the four models
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19 Oct 1979; 11 p; Symposium on the scientific basis for nuclear waste management; Boston, MA, USA; 26 - 29 Nov 1979; CONF-791112--9; Available from NTIS., PC A02/MF A01
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