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AbstractAbstract
[en] A preliminary report is presented on the effect of correlation in the 3d/sup n/ core on the 3d101S → 3d9 4p 1P f value by use of the multiconfiguration (MC) Hartree-Fock procedure. A common orbital basis was used for correlation in the core, with virtual orbitals determined variationally for the initial state. Three different approximations were used: a single-configuration approximation for both initial and final state, a MC approximation for 3d10 correlation in the initial state and a single configuration for the final state, and MC approximations for both initial and final states. Some preliminary f values for the 3d101S → 3d9 4p 1P transition are tabulated. Comparison of calculated with experimental values indicates that correlation in the 3d9 core of the final state is needed to obtain the correct transition energy to bring the length and velocity forms into good agreement with themselves and experiment, and that the multiplet strength for the transition is not greatly affected by correlation. 1 table
Original Title
Multiconfiguration Hartree-Fock
Primary Subject
Source
1979; 6 p; 46. Nobel symposium on many-body theory of atomic systems; Aspenasgarden, Lerum, Sweden; 11 - 16 Jun 1979; CONF-7906128--3; Available from NTIS., PC A02/MF A01
Record Type
Report
Literature Type
Conference; Numerical Data
Report Number
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