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AbstractAbstract
[en] ZrC coatings by chemical vapor deposition were applied to particles of ThO2, UO2 and Al2O3 at 1623-1873 K. The feed gas mixture consisted of ZrBr4, CH4, H2 and Ar. The results were compared with the calculated chemical equilibria in the Zr-C-H-Br system. It was shown that the weight and composition of the deposit can be calculated by thermochemical analysis after correcting the methane flow rate for a pyrolysis efficiency. Predominant reaction presumably occurring were derived by a mass balance consideration on the calculated equilibrium species. A simplified model of the ZrC deposition was proposed. (orig.)
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Journal Article
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Journal of Nuclear Materials; ISSN 0022-3115;
; v. 97(1/2); p. 104-112

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