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AbstractAbstract
[en] Photoionization of H2(1Σsub(g)+) in a vibrational upsilon'' and rotational NU'' state into H2+(2Σsub(g)+) in a vibrational upsilon' and rotational NU' state is studied theoretically. Parallel expressions are obtained for H2+ in a specific upsilon' state and for H2+ in a rotational fine level upsilon'NU'. Asymmetry parameters β, β(upsilon') and β(upsilon'NU') which are expressed in terms of Racah and Clebsch-Gordan coefficients and electronic transition moments, can be reduced approximately to 2 for linearly polarized light and to -1 for unpolarized light. Using single-center electronic wave functions and including partial waves l = 1, 3, and 5, σ(upsilon') and β(upsilon') are computed as a function of upsilon' at 584A. The computed σ(upsilon') divided by the Frank-Gondon overlap, in agreement with experimental results, increases monotonically with upsilon'; σsub(T) and β are computed in the incident photon energy range of 600-400 A and the results compare favorably with previous calculations. (author)
Primary Subject
Record Type
Journal Article
Literature Type
Numerical Data
Journal
Journal of Quantitative Spectroscopy and Radiative Transfer; ISSN 0022-4073;
; v. 25(3); p. 253-264

Country of publication
ANGULAR DISTRIBUTION, CLEBSCH-GORDAN COEFFICIENTS, DIFFERENTIAL CROSS SECTIONS, ELECTRONS, ENERGY-LEVEL TRANSITIONS, FRANCK-CONDON PRINCIPLE, HYDROGEN, HYDROGEN IONS 2 PLUS, MOLECULES, PARTIAL WAVES, PHOTOIONIZATION, PHOTON-MOLECULE COLLISIONS, RACAH COEFFICIENTS, ROTATIONAL STATES, THEORETICAL DATA, VIBRATIONAL STATES, WAVE FUNCTIONS
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