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AbstractAbstract
[en] Two series of complexes of meconic acid (H3Mec) with rare-earths have been prepared by varying the preparative procedure. The compounds have the general formulae, [Ln(Mec) (H2O)2].3 H2O (where Ln = La, Ce, Pr, Nd, Sm, Ho and Y) and [Ln(HMec) (H2Mec) (H2O)2].4 H2O (where Ln = La, Pr, Nd and Sm). The infrared spectral data indicate that the carboxylate groups are bound to the rare-earth metal in a bidentate fashion. Thermal studies indicate that two water molecules are coordinated in each case. The complexes are probably polymeric. (author)
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Monatshefte fuer Chemie; ISSN 0026-9247;
; v. 112(2); p. 167-173

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