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AbstractAbstract
[en] The solvent extraction behaviour of Am(III) from dilute nitric acid media with sulfoxides (R2SO) in Solvesso-100 has been investigated over a wide range of conditions. The very poor extractability of Am necessitated the use of salting-out agents, viz., nitrates of Al, Mg, Ca, Li and NH4+. The effects of certain variables such as acidity, extractant concentration, salting-out agent, temperature etc., on metal extraction by sulfoxides have been examined systematically. For a fixed sulfoxides concentration, extraction attains a maximum value up to around 0.2-0.4M HNO3 and decreasing above 1M HNO3. In contrast, increasing the concentration of sulfoxide (0.8M DISO, 1.3M DBuSO) gives almost quantitative Am extraction up to 1M HNO3. For satisfactory extraction, di-n-octyl as well as di-n-hexyl sulfoxide are the most suitable extracting agents. The extractability of Am increases with increasing amounts of all the salting-out agents studied and their effect follows the sequence: Al3+>Mg2+>Ca2+>Li+>NH4+; this is also the relative dehydrating effect of the cations. The species extracted would appear to be Am(NO3)3x3R2SO. Americium is easily stripped with 1-3M HNO3 solutions from the loaded organic phase. The extraction decreases with increasing temperature, indicating the extraction to be exothermic. The extraction from partially non-aqueous solutions was also investigated. (author)
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32 refs.
Record Type
Journal Article
Journal
Journal of Radioanalytical Chemistry; ISSN 0134-0719;
; v. 62(1-2); p. 61-72

Country of publication
ACTINIDE COMPLEXES, ACTINIDE NUCLEI, ALPHA DECAY RADIOISOTOPES, AMERICIUM ISOTOPES, COMPLEXES, DISPERSIONS, HEAVY NUCLEI, HOMOGENEOUS MIXTURES, HYDROGEN COMPOUNDS, INORGANIC ACIDS, ISOTOPE APPLICATIONS, ISOTOPES, MIXTURES, NITROGEN COMPOUNDS, NUCLEI, ODD-EVEN NUCLEI, ORGANIC COMPOUNDS, ORGANIC SULFUR COMPOUNDS, OXYGEN COMPOUNDS, RADIOISOTOPES, SEPARATION PROCESSES, SOLUTIONS, TRANSURANIUM COMPLEXES, YEARS LIVING RADIOISOTOPES
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