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Miller, H.H.; Bissell, E.R.; Tsugawa, R.T.; Souers, P.C.
Proceedings: tritium technology in fission, fusion, and isotopic applications1980
Proceedings: tritium technology in fission, fusion, and isotopic applications1980
AbstractAbstract
[en] Research on the acetylene compound 1,4-diphenylbutadiyne is an effort to develop a tritium gas getter that will operate in the presence of air and minimize the formation of water. T2 adds to the acetylene bond of the getter in the presence of a metal catalyst. The catalyst stimulates the T2-O2 reaction as well. The butadiyne compound has shown good reaction efficiency for 300 ppM T2 in static dry air at room temperature and one atmosphere pressure. Metalacetylene complexes are being synthesized, positioning the metal catalyst atom as close to the triple bond as possible to maximize the organic reaction. Organometallics such as triphenyl phosphine iridium are being investigated as possible regenerative getters for T2 in air. Gas mixtures as low as 1 ppM T2 in air will be tested under flow conditions in future work
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Wittenberg, L.J. (comp.); p. 208-212; 1980; p. 208-212; American Nuclear Society; La Grange Park, IL; Tritium technology in fission, fusion, and isotopic applications; Dayton, OH, USA; 29 Apr - 1 May 1980
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