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AbstractAbstract
[en] The creep of UO2 containing small additions of Nb2O5 has been investigated in the stress range 0.5-90 MN/m2 at temperatures between 1422 and 1573 K. The functional dependence of the creep rate of five dopant concentrations up to 0.8 mol% Nb2O5 has been examined and it was established that in all the materials the secondary creep rate could be represented by the equation epsilonkT = Asigmasup(n) exp(-Q/RT), where epsilon is the steady state creep rate per hour, Q the activation energy and A and n are constants for each material. It was observed that Nb2O5 additions can cause a dramatic increase in the steady state creep rate as long as the niobium ion is maintainde in the Nb5+ valence state. Material containing 0.4 mol% Nb2O5 creeps three orders of magnitude faster than the pure material. Analysis of the results in terms of grain size compensated viscosity suggest that, like pure UO2, the creep rate of Nb2O5 doped fuel is diffusion-controlled and proportional to the reciprocal square of the grain size. A model is developed which suggests that the increase in creep rate results from suppression of the U5+ ion concentration by the addition of Nb5+ ions, which modifies the crystal defect structure and hence the uranium ion diffusion coefficient. (orig.)
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Journal Article
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Journal of Nuclear Materials; ISSN 0022-3115;
; v. 97(3); p. 300-308

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