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AbstractAbstract
[en] The 5s25p 2P(3/2) - 5s2ns2S(1/2), 5s2nd2D(3/2,5/2) Rydberg series (25 <= n <= 107) in indium have been investigated with high precision. The atoms were excited in an atomic beam by a frequency-doubled pulsed dye laser (lambda approx. 225 nm). The highly excited atoms were detected using the field ionization technique. The ionization limit has been determined at 46 670.107 +- 0.010 cm-1 from the 2S series. The perturbation of the 2D series due to configuration interaction with the 2D term of the 5s5p2 configuration has been studied. Discrepancies with previous observations of these series are discussed. The fine structure splitting of the 2D levels could be determined up to n = 70. It is found to be almost proportional to nsup(*)-3 over the range observed, but the size of the splitting is strongly affected by the perturbation. A description of the effects is presented in the framework of perturbation theory with Hartree-Fock values as a first order approximation. Level values for the 5s5p22D(3/2,5/2) levels are predicted and compared with observations. (orig.)
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Journal Article
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Physica B plus C; ISSN 0378-4363;
; v. 106(2); p. 271-286

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