[en] Rotational level populations of N₂ were measured downstream from the skimmer in beams of pure N₂ and in mixtures of N₂ with He, Ne, and Ar expanded from room temperature nozzles. The range of p₀D was from 5 to 50 Torr cm. The formation of dimers and higher condensates of beam species was monitored during the runs. The effect of condensation energy release on rotational populations and parallel temperatures was readily observed. Two different methods for evaluating the rotational population distributions were compared. One method is based on a dipole-excitation model and the other on an excitation matrix obtained empirically. Neither method proved clearly superior. Both methods indicated nonequilibrium rotational populations for all of our room temperature nozzle expansion conditions. Much of the nonequilibrium character appears to be due to the behavior of the K = 2 and K = 4 levels, which may be accounted for in terms of the rotational energy level spacing. In particular, the overpopulation of the K = 4 level is explained by a near-resonant transfer of rotational energy between molecules in the K = 6 and K = 0 states, to give two molecules in the K = 4 state. Rotational and vibrational temperatures were determined for pure N₂ beams from nozzles heated up to 1700 ⁰K. The heated nozzle experiments indicated a 40% increase in the rotational collision number between 300 and 1700 ⁰K