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Causey, R.A.; Wichner, R.P.
Oak Ridge National Lab., TN (USA); Virginia Univ., Charlottesville (USA)1981
Oak Ridge National Lab., TN (USA); Virginia Univ., Charlottesville (USA)1981
AbstractAbstract
[en] Diffusion profiles have been measured for silver in hollow and solid cylinders in the temperature range 490 to 8000C. The profiles show two components of diffusion. There is a high concentration, relatively immobile zone near the surface and a low concentration, rapidly moving component deeper into the sample. The rapid component is well fitted by the diffusion equation when irreversible trapping is assumed. The diffusion coefficients determined by least-square analysis of the profiles can be represented by D (m2/sec) = 17.4 exp (-22,100/T). Excessive scatter was seen in the trapping coefficients determined from the profiles. This is believed to be due to varying amounts of impurities in the different samples. A limited number of desorption measurements were performed for silver from H-451 graphite. Evidence of Elovich-type behavior was noted
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1981; 4 p; Colloquium on the transport of fission products in matrix and graphite; Berlin, Germany, F.R; 9 - 11 Nov 1981; Available from NTIS., PC A02/MF A01 as DE82004050
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