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Egnell, J.; Larsen, J.G.; Moeller, L.; Roed, G.
Swedish Nuclear Fuel Supply Co., Stockholm1981
Swedish Nuclear Fuel Supply Co., Stockholm1981
AbstractAbstract
[en] Metastable liquid-liquid separation in glasses can often cause significant changes in physical and chemical properties of the original homogeneous glass. In some technical borosilicate glasses this phenomenon is used to change the chemical durability of the glass. For potential nuclear-waste-glasses the slow cooling through the temperature range 5500C - 7000C may lead to such a liquid-liquid phase separation. In order to investigate the susceptibility of phase separation of nuclear-waste-glasses, two KBS model glasses, ABS-39 and ABS-41, were investigated. Two of the subsequent reports are concerned with this problem. The third report also takes into consideration the effects of MoO3 on the immiscibility gap. The maximum amount of MoO3 that can be dissolved in ABS-39 and ABS 41 is also determined. (Auth.)
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Dec 1981; 48 p; Made up of 3 reports of work financed by SKBF, peformed at the Technical University of Denmark.
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