Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.018 seconds
Speranzini, R.A.; Buckley, L.P.
Atomic Energy of Canada Ltd., Chalk River, Ontario. Chalk River Nuclear Labs1981
Atomic Energy of Canada Ltd., Chalk River, Ontario. Chalk River Nuclear Labs1981
AbstractAbstract
[en] Ion-exchange resins are used in CANDU-PHW nuclear power stations to purify heavy water in the primary heat transport (PHT) and moderator systems. Two techniques for conditioning spent ion-exchange resins for disposal have been evaluated: direct immobilization, and incineration combined with immobilization of the ash and scrubbed off-gases. When ion-exchange resins were immobilized directly, no volume reductions were obtained at the various resin-to-matrix weight ratios attempted. Volumes of bitumen and glass products were equal to the volumes of untreated resin while the volumes of cement and polyester products were two and three times larger. While incinerating the resin is an extra processing step, high reductions in volume result. Bitumen and glass product volumes were six times smaller than the volumes of untreated resin while cement and polyster product volumes were about half the volume of untreated resin. Since the releases of Cs-137 were about ten times lower for products made by direct immobilization, PHT resins, which have high concentrations of Cs-137, should be immobilized directly. Moderator resins which have high concentrations of C-14 should be incinerated and the ash- and C-14-contaminated scrubbing solutions should be immobilized. By pretreating such resins with calcium chloride, the C-14 present on resin could be released at temperatures below the ignition temperature of the resin. This technique reduces the amount of inactive carbon dioxide that must be scrubbed to trap the C-14. The releases of C-14 from immobilized barium hydroxide scrubbing solution were the same as releases from immobilized resin
Primary Subject
Source
Sep 1981; 46 p; 2. IAEA research coordination meeting on treatment of spent ion-exchange resins; Toronto, Ontario, Canada; 21 - 25 Sep 1981
Record Type
Report
Literature Type
Conference
Report Number
Country of publication
ASHES, BARIUM HYDROXIDES, BITUMENS, CALCIUM CHLORIDES, CARBON 14, CARBON DIOXIDE, CEMENTS, CESIUM 137, COMBUSTION, GASEOUS WASTES, GLASS, ION EXCHANGE MATERIALS, LEACHING, MODERATORS, ORGANIC ION EXCHANGERS, POLYESTERS, PRIMARY COOLANT CIRCUITS, RADIOACTIVE WASTE PROCESSING, RESINS, SOLUTIONS, VOLUME
ALKALINE EARTH METAL COMPOUNDS, BARIUM COMPOUNDS, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, BUILDING MATERIALS, CALCIUM COMPOUNDS, CARBON COMPOUNDS, CARBON ISOTOPES, CARBON OXIDES, CESIUM ISOTOPES, CHALCOGENIDES, CHEMICAL REACTIONS, CHLORIDES, CHLORINE COMPOUNDS, COOLING SYSTEMS, DISPERSIONS, DISSOLUTION, ESTERS, EVEN-EVEN NUCLEI, HALIDES, HALOGEN COMPOUNDS, HOMOGENEOUS MIXTURES, HYDROGEN COMPOUNDS, HYDROXIDES, INTERMEDIATE MASS NUCLEI, ISOTOPES, LIGHT NUCLEI, MANAGEMENT, MIXTURES, NUCLEI, ODD-EVEN NUCLEI, ORGANIC COMPOUNDS, ORGANIC POLYMERS, OTHER ORGANIC COMPOUNDS, OXIDATION, OXIDES, OXYGEN COMPOUNDS, POLYMERS, RADIOISOTOPES, REACTOR COMPONENTS, REACTOR COOLING SYSTEMS, SEPARATION PROCESSES, SOLID WASTES, TAR, WASTE MANAGEMENT, WASTE PROCESSING, WASTES, YEARS LIVING RADIOISOTOPES
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue