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AbstractAbstract
[en] The iodine-containing species in an intact fuel particle in the high-temperature gas-cooled reactor (HTGR) have been calculated. Assumptions include: (1) attainment of chemical thermodynamic equilibrium among all species in the open porosity of the particle, primarily in the buffer layer; and (2) fission-product concentrations in proportion to their yields. The primary gaseous species is calculated to be cesium iodide; in carbide-containing fuels, gaseous barium iodide may exhibit equivalent pressures. The condensed iodine-containing phase is usually cesium iodide, but in carbide-containing fuels, barium iodide may be stable instead. Absorption of elemental iodine on the carbon in the particle appears to be less than or equal to 10-4 μg I/g C. The fission-product-spectra excess of cesium over iodine would generally be adsorbed on the carbon, but may form Cs2MoO4 under some circumstances
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Sep 1982; 23 p; Available from NTIS., PC A02/MF A01 as DE83000379
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