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Harker, A.B.; Morgan, P.E.D.; Clarke, D.R.; Flintoff, J.J.; Shaw, T.M.
Development of polyphase ceramics for the immobilization of high-level Defense nuclear waste1983
Development of polyphase ceramics for the immobilization of high-level Defense nuclear waste1983
AbstractAbstract
[en] An improved ceramic nuclear waste form and fabrication process have been developed using simulated Savannah River Plant defense high-level waste compositions. The waste form provides flexibility with respect to processing conditions while exhibiting superior resistance to ground water leaching than other currently proposed forms. The ceramic, consolidated by hot-isostatic pressing at 10400C and 10,000 psi, is composed of six major phases, nepheline, zirconolite, a murataite-type cubic phase, magnetite-type spinel, a magnetoplumbite solid solution, and perovskite. The waste form provides multiple crystal lattice sites for the waste elements, minimizes amorphous intergranular material, and can accommodate waste loadings in excess of 60 wt %. The fabrication of the ceramic can be accomplished with existing manufacturing technology and eliminates the effects of radionuclide volatilization and off-gas induced corrosion experienced with the molten processes for vitreous form production
Original Title
RSC-S29 ceramics
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Morgan, P.E.D.; Harker, A.B.; Clarke, D.R.; Flintoff, J.J.; Shaw, T.M.; Rockwell International Corp., Thousand Oaks, CA (USA). Science Center; p. 5-46; 25 Feb 1983; p. 5-46; Available from NTIS, PC A06/MF A01 as DE83007892
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