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Serne, R.J.; Peterson, S.R.; Gee, G.W.
Pacific Northwest Lab., Richland, WA (USA)1983
Pacific Northwest Lab., Richland, WA (USA)1983
AbstractAbstract
[en] We discuss FY82 progress on the development of laboratory tools to aid in the prediction of migration potential of contaminants present in acidic uranium mill tailings leachate. Further, empirical data on trace metal and radionuclide migration through a clay liner are presented. Acidic uranium mill tailings solution from a Wyoming mill was percolated through a composite sediment called Morton Ranch Clay liner. These laboratory columns and subsequent sediment extraction data show: (1) As, Cr, Pb, Ag, Th and V migrate very slowly; (2) U, Cd, Ni, Zn, Fe, Mn and similar transition metals are initially immobilized during acid neutralization but later are remobilized as the tailings solution exhausts the clay liner's acid buffering capacity. Such metals remain immobilized as long as the effluent pH remains above a pH value of 4 to 4.5, but they become mobile once the effluent pH drops below this range; and (3) fractions of the Se and Mo present in the influent tailings solution are very mobile. Possible controlling mechanisms for the pH-dependent immobilization-mobilization of the trace metals are discussed. More study is required to understand the controlling mechanisms for Se and Mo and Ra for which data were not successfully collected. Using several column lengths (from 4.5 to 65 cm) and pore volume residence times (from 0.8 to 40 days) we found no significant differences in contaminant migration rates or types and extent of controlling processes. Thus, we conclude that the laboratory results may be capable of extrapolation to actual disposal site conditions
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Apr 1983; 124 p; PNL--4605; Available from NTIS, PC A06/MF A01; 1 - GPO $6.00 as DE83010802
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ACTINIDES, DATA, DISPERSIONS, ELEMENTS, ENVIRONMENTAL TRANSPORT, HOMOGENEOUS MIXTURES, HYDROGEN COMPOUNDS, INFORMATION, MANAGEMENT, MASS TRANSFER, METALS, MINERALS, MIXTURES, NUMERICAL DATA, OXYGEN COMPOUNDS, SEMIMETALS, SOLID WASTES, SOLUTIONS, TRANSITION ELEMENTS, WASTE DISPOSAL, WASTE MANAGEMENT, WASTES, WATER
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