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Graham, L.W.; Brenner, K.G.E.
Metallic materials for heat exchanger components and highly stressed internal of HTR reactors for nuclear process heat generation1982
Metallic materials for heat exchanger components and highly stressed internal of HTR reactors for nuclear process heat generation1982
AbstractAbstract
[en] Due to the presence of H2, H2O, CO and CH4 in impure helium environments surface reactions can occur causing oxidation, decarburisation or carburisation depending on the detailed level of impurities. The interplay between these different corrosion regimes can be represented on a Ternary Environmental Attack (TEA) diagram which shows that gas compositions causing decarburisation are separated from those causing carburisation by an area in which a protective Cr-based oxide is formed. This area gives protective oxides and represents the desirable composition range for HTR systems and it is argued that due to the presence of a hot graphite core, impurity levels in HTR systems will tend to fall in the protective corrosion regime at least up to a temperature of 9000C. In any case, the TEA diagram provides a basis for developing methods for controlling impurity levels in an operating system to give acceptable corrosion behaviour. Experiments performed for periods of about 10000 h within the protective regime and in the lower band of gas composition specified as the reference PNP-Test-Helium environment show that the reference PNP alloys possess excellent corrosion resistance at 9000C. (orig.)
Original Title
Ueberblick ueber Korrosionserscheinungen in HTR-Helium
Primary Subject
Secondary Subject
Source
Ministerium fuer Wirtschaft, Mittelstand und Verkehr des Landes Nordrhein-Westfalen, Duesseldorf (Germany, F.R.); Energiepolitik in Nordrhein-Westfalen; v. 14; 359 p; 1982; p. 45-62; Status seminar at the Ministry for Economics, Trade and Transportation of the Land of North Rhine Westphalia; Duesseldorf (Germany, F.R.); 14-15 Jan 1982
Record Type
Miscellaneous
Literature Type
Conference
Report Number
Country of publication
CARBON MONOXIDE, CARBURIZATION, CHEMICAL COMPOSITION, CHEMICAL REACTIONS, CHROMIUM OXIDES, CORROSION, DECARBURIZATION, DIAGRAMS, GRAPHITE, HASTELLOY X, HELIUM, HTGR TYPE REACTORS, HYDROGEN, IMPURITIES, INCONEL 617, METHANE, NIMONIC 86, OXIDATION, PROCESS HEAT REACTORS, PROTECTIVE COATINGS, REACTOR CORES, SURFACES, TEMPERATURE DEPENDENCE, VERY HIGH TEMPERATURE, WATER VAPOR
ALKANES, ALLOYS, ALUMINIUM ALLOYS, CARBON, CARBON ADDITIONS, CARBON COMPOUNDS, CARBON OXIDES, CHALCOGENIDES, CHROMIUM ALLOYS, CHROMIUM COMPOUNDS, COATINGS, COBALT ALLOYS, ELEMENTS, FLUIDS, GAS COOLED REACTORS, GASES, GRAPHITE MODERATED REACTORS, HARDENING, HASTELLOYS, HEAT RESISTING ALLOYS, HYDROCARBONS, INCONEL ALLOYS, INFORMATION, IRON ALLOYS, MANGANESE ADDITIONS, MOLYBDENUM ALLOYS, NICKEL ALLOYS, NICKEL BASE ALLOYS, NIMONIC, NONMETALS, ORGANIC COMPOUNDS, OXIDES, OXYGEN COMPOUNDS, POWER REACTORS, RARE GASES, REACTOR COMPONENTS, REACTORS, SILICON ADDITIONS, SURFACE HARDENING, SURFACE TREATMENTS, TITANIUM ADDITIONS, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENT COMPOUNDS, TUNGSTEN ALLOYS, VAPORS
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