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AbstractAbstract
[en] The chemical erosion of C, TiB2, and TiC by reaction with H has been studied from 420 to 1540 K using H pressures characteristic of fusion devices. For graphite, erosion yields range from 2.0 x 10-4 to 7.4 x 10-4 C/H over this temperature range. A change in the gas phase product distribution is observed as a function of temperature and reaction time. Methane is most abundant at low temperatures and short reaction times, while C2 and C3 species increase in abundance at higher temperatures and after extended reaction times. For C-rich TiC, initial behavior is similar to graphite, but the time evolution of gas phase products differs. TiB2 shows no evidence of reaction below 1300 K and lower erosion yields than graphite at higher temperatures. The superior erosion resistance of TiB2 suggests that it may be a better candidate material than graphite for fusion applications requiring refractory low-Z materials
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1983; 15 p; 3. topical meeting on fusion reactor materials; Albuquerque, NM (USA); 19-23 Sep 1983; CONF-830942--2; Available from NTIS, PC A02/MF A01 as DE83017161
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