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AbstractAbstract
[en] As part of the Nuclear Regulatory Commission's requirement to assess the Department of Energy's application to construct geologic repositories for high-level radioactive waste, Battelle's Columbus Laboratories is investigating the long-term performance of materials used for high-level waste packages. The effects on glass waste-form dissolution of temperature, pressure, solution chemistry, and ratio of glass surface area to solution volume have been studied. The glass-dissolution correlation is ready to be evaluated by comparison with experiments. The devitrification correlation has been completed. In canister-corrosion studies, CF8 alloy was found less susceptible to glass attack than Type 304L stainless steel. Limited experiments revealed no corrosion mechanism which would indicate that cast steel could not be used as a corrosion-allowance container material; additional tests with cracking agents are planned. In hydrogen-uptake studies, cast steel was found to absorb more hydrogen than wrought steel. Parts of the general-corrosion correlation have been tested, and work continues on obtaining realistic experimental data as input for it. Gamma fluxes and dose rates in and near the waste package were calculated for CHLW and spent-fuel waste forms. The current water-radiolysis model was found adequate when tested against existing data, and preliminary calculations were performed with the current water-chemistry model; in both cases, additional chemical species are being incorporated. This report documents investigations performed during the period April, 1983 to April, 1984
Primary Subject
Source
Jun 1984; 281 p; BMI--2113-VOL.4; Available from NTIS, PC A13/MF A01 - GPO* $7.00 as TI84901512
Record Type
Report
Literature Type
Numerical Data; Progress Report
Report Number
Country of publication
CHEMISTRY, CORROSION, DISSOLUTION, EMBRITTLEMENT, EXPERIMENTAL DATA, GAMMA RADIATION, GEOLOGIC DEPOSITS, GLASS, HIGH-LEVEL RADIOACTIVE WASTES, HYDROGEN ADDITIONS, PACKAGING, PRESSURE DEPENDENCE, RADIATION DOSES, RADIOACTIVE WASTE DISPOSAL, RADIOLYSIS, SIZE, SPENT FUEL ELEMENTS, STEEL-CR19NI10, STEELS, SURFACES, TEMPERATURE DEPENDENCE, THEORETICAL DATA, UNDERGROUND DISPOSAL, WATER
ALLOYS, AUSTENITIC STEELS, CARBON ADDITIONS, CHEMICAL RADIATION EFFECTS, CHEMICAL REACTIONS, CHROMIUM ALLOYS, CHROMIUM-NICKEL STEELS, CORROSION RESISTANT ALLOYS, DATA, DECOMPOSITION, ELECTROMAGNETIC RADIATION, FUEL ELEMENTS, HEAT RESISTING ALLOYS, HIGH ALLOY STEELS, HYDROGEN COMPOUNDS, INFORMATION, IONIZING RADIATIONS, IRON ALLOYS, IRON BASE ALLOYS, MANAGEMENT, MATERIALS, NICKEL ALLOYS, NUMERICAL DATA, OXYGEN COMPOUNDS, RADIATION EFFECTS, RADIATIONS, RADIOACTIVE MATERIALS, RADIOACTIVE WASTES, REACTOR COMPONENTS, STAINLESS STEELS, WASTE DISPOSAL, WASTE MANAGEMENT, WASTES
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