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Hughes, M.R.; Nolan, T.A.
Oak Ridge Gaseous Diffusion Plant, TN (USA)1984
Oak Ridge Gaseous Diffusion Plant, TN (USA)1984
AbstractAbstract
[en] Laboratory experiments to quantify uranium compound deposition on Aluminum 3003 test coupons have been initiated. These experiments consist of exposing the coupons to normal assay UF6 (0.7% 235U) in nickel reaction vessels under various conditions of UF6 pressure, temperature, and time. To-date, runs from 5 minutes to 2000 hr have been completed at a UF6 pressure of 100 torr and at a temperature of 600C. Longer exposure times are in progress. Initial results indicated that a surface film of uranium, primarily as uranyl fluoride (UO2F2), is deposited very soon after exposure to UF6. In a five minute UF6 exposure at a temperature of 600C, an average of 2.9 μg U/cm2 was deposited; after 24 hr the deposit typically increased to 5.0 μg/cm2 and then increased to 10.4 μg/cm2 after 2000 hr. This amount of deposit (at 2000 hr exposure) would contribute roughly 10 to 20% to the total 186 keV gamma signal obtained from a GCEP product header pipe being operated at UF6 pressures of 2 to 5 torr. The amount of isotopic exchange which would occur in the deposit in the event that HEU and LEU productions were alternated is considered. It is felt that isotopic exchange would not occur to any significant amount within the fixed deposit during relatively short HEU production periods since the HEU would be present primarily as adsorbed UF6 molecules on the surface of the deposit. The adsorbed HEU molecules would be removed by evacuation and diluted by LEU production. Major increases in the deposit count would be observed if a leak occurred or moisture was introduced into the system while HEU was being produced
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19 Jun 1984; 18 p; Available from NTIS, PC A02/MF A01 as DE84017575
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