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Kasper, R.B.; Delegard, C.H.
Rockwell International Corp., Richland, WA (USA). Rockwell Hanford Operations1984
Rockwell International Corp., Richland, WA (USA). Rockwell Hanford Operations1984
AbstractAbstract
[en] Studies at Oak Ridge National Laboratory indicate that trace quantities of certain actinide elements are migrating from waste disposal trenches in part as Ethylenediaminetetraacetic Acid (EDTA) complexes. Some of the strongest actinide complexes are formed by EDTA and related chelating agents. To some extent, the actinides are sorbed by the soil and a positive correlation is observed between the concentration of manganese on the surface of the soil particles and the concentration of the sorbed actinides. While manganese oxides have long been recognized as important scavengers of trace metals in the environment, sorption of an actinide element from a strong chelated complex has not been previously indicated. Batch experiments were performed to evaluate the sorption of a plutonium-EDTA complex by manganese oxide. The manganese oxide was prepared as an amorphous coating on synthetic fibers following the procedure of Moore. The prepared fiber was contacted by several nitrate solutions containing different concentrations of calcium, sodium, and EDTA to evaluate the effect of competing cations, ionic strength of solution, and concentration of complexing agent. All solutions were spiked with approximately 10-7 molar of 238Pu. For all solutions, generally greater than 95% of the plutonium was sorbed by the manganese oxide-coated fibers after contact times of 10 minutes. In all cases using the manganese oxide-coated fibers, after 100 minutes of contact time, greater than 99% of the plutonium was removed from solution. For one experiment using a solution spiked with approximately 10-7 molar of 241Am, sorption of americium was found to be significantly slower than sorption of plutonium. Greater than 99% of the americium was removed from the solution only after approximately 10,000 minutes. Although the mechanism has not been established, manganese oxide was shown to sorb plutonium and americium from, or as, an EDTA complex. 22 references, 5 figures
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Source
1984; 21 p; 97. annual meeting and exposition of the Geological Society of America; Reno, NV (USA); 5-8 Nov 1984; CONF-841145--1; Available from NTIS, PC A02/MF A01 as DE85006084
Record Type
Report
Literature Type
Conference; Numerical Data
Report Number
Country of publication
ACTINIDE NUCLEI, ALPHA DECAY RADIOISOTOPES, AMERICIUM ISOTOPES, AMINO ACIDS, CARBOXYLIC ACIDS, CHALCOGENIDES, CHELATING AGENTS, DATA, ELEMENTS, EVEN-EVEN NUCLEI, HEAVY NUCLEI, INFORMATION, ISOTOPES, MANGANESE COMPOUNDS, METALS, NUCLEI, NUMERICAL DATA, ODD-EVEN NUCLEI, ORGANIC ACIDS, ORGANIC COMPOUNDS, OXIDES, OXYGEN COMPOUNDS, PLUTONIUM ISOTOPES, RADIOISOTOPES, TRANSITION ELEMENT COMPOUNDS, YEARS LIVING RADIOISOTOPES
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