[en] Recent studies have shown that significant compositional redistribution in irradiated alloys can be induced by the gradients in the atomic displacement rates resulting from nonuniform defect production, in addition to the commonly-observed solute segregation at defect sinks. This process gives rise to complex local phase transformations during light-ion bombardment or irradiation with focused electron beams in the high-voltage electron microscope. Results of our theoretical and experimental investigations of this phenomenon in Ni-Al and Ni-Si are discussed. The implications of the observed effect in a number of areas of materials science are assessed