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Warren, J.L.; Zerwekh, A.
Los Alamos National Lab., NM (USA)1985
Los Alamos National Lab., NM (USA)1985
AbstractAbstract
[en] As part of a TRU waste-sampling program, Los Alamos National Laboratory retrieved and examined 44 drums of 238Pu- and 239Pu-contaminated waste. The drums ranged in age from 8 months to 9 years. The majority of drums were tested for pressure, and gas samples withdrawn from the drums were analyzed by a mass spectrometer. Real-time radiography and visual examination were used to determine both void volumes and waste content. Drum walls were measured for deterioration, and selected drum contents were reassayed for comparison with original assays and WIPP criteria. Each drum tested at atmospheric pressure. Mass spectrometry revealed no problem with 239Pu-contaminated waste, but three 8-month-old drums of 238Pu-contaminated waste contained a potentially hazardous gas mixture. Void volumes fell within the 81 to 97% range. Measurements of drum walls showed no significant corrosion or deterioration. All reassayed contents were within WIPP waste acceptance criteria. Five of the drums opened and examined (15%) could not be certified as packaged. Three contained free liquids, one had corrosive materials, and one had too much unstabilized particulate. Eleven drums had the wrong (or not the most appropriate) waste code. In many cases, disposal volumes had been inefficiently used. 2 refs., 23 figs., 7 tabs
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Aug 1985; 94 p; Available from NTIS, PC A05/MF A01; 1 as DE86003281
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ACTINIDE NUCLEI, ALPHA DECAY RADIOISOTOPES, CHEMICAL ANALYSIS, CHEMICAL RADIATION EFFECTS, CHEMICAL REACTIONS, DATA, DECOMPOSITION, DISPERSIONS, EVEN-EVEN NUCLEI, EVEN-ODD NUCLEI, HEAVY NUCLEI, INFORMATION, ISOTOPES, MANAGEMENT, MATERIALS, MIXTURES, NUCLEI, NUMERICAL DATA, PLUTONIUM ISOTOPES, RADIATION EFFECTS, RADIOACTIVE MATERIALS, RADIOACTIVE WASTES, RADIOISOTOPES, SPECTROSCOPY, STORAGE, SUSPENSIONS, WASTE MANAGEMENT, WASTE STORAGE, WASTES, YEARS LIVING RADIOISOTOPES
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