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Mailen, J.C.; Tallent, O.K.
Oak Ridge National Lab., TN (USA)1986
Oak Ridge National Lab., TN (USA)1986
AbstractAbstract
[en] A number of solid sorbents were tested for the removal of uranium and dibutyl phosphate (DBP) from 30% tributyl phosphate (TBP) solvent. The desired clean uranium product can be obtained either by removing the DBP, leaving the uranium in the solvent for subsequent stripping, or by removing the uranium, leaving the DBP in the solvent for subsequent treatment. The tests performed show that it is relatively easy to preferentially remove uranium from solvents containing uranium and DBP, but quite difficult to remove DBP preferentially. The current methods could be used by removing the uranium (as by a cation exchange resin) and then using either an anion exchange resin in the hydroxyl form or a conventional treatment with a basic solution to remove the DBP. Treatment of a solvent with a cation exchange resin could be useful for recovery of valuable metals from solvents containing DBP and might be used to remove cations before scrubbing a solvent with a basic solution to minimize emulsion formation. 6 refs., 9 figs
Primary Subject
Source
1986; 35 p; 1. international conference on separations science and technology; New York, NY (USA); 16-18 Apr 1986; Available from NTIS, PC A03/MF A01; 1 as DE86008222; Portions of this document are illegible in microfiche products.
Record Type
Report
Literature Type
Conference; Numerical Data
Report Number
Country of publication
ACTINIDES, ALUMINIUM COMPOUNDS, BUTYL PHOSPHATES, CHALCOGENIDES, DATA, ELEMENTS, ENERGY SOURCES, ESTERS, FUELS, INFORMATION, MANAGEMENT, MATERIALS, METALS, NUCLEAR FUELS, NUMERICAL DATA, ORGANIC COMPOUNDS, ORGANIC PHOSPHORUS COMPOUNDS, ORGANIC POLYMERS, OXIDES, OXYGEN COMPOUNDS, PHOSPHORIC ACID ESTERS, POLYMERS, REACTOR MATERIALS, REPROCESSING, SEPARATION PROCESSES, TRANSURANIUM ELEMENTS, WASTE MANAGEMENT
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