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AbstractAbstract
[en] The composition of the products of carbothermal reduction of Sc2O3 is examined by X-ray diffraction and chemical analysis and by the hydrolysis method. At pressures of 10-2-1 Pa, the reaction starts in the temperature region of 1000 - 1200 oC. The first product is Sc2OC of NaCl type; at 1 Pa and 1400 - 1500 oC this substance is formed quantitatively (according to stoichiometry) within 50 - 100 h, repeated homogenization, however, is necessary, or else Sc2OC reacts locally with Sc2O3 giving Sc2O1+xC1-x. The lattice parameter of Sc2OC in the presence of Sc15C19 is 457.63pm. At temperatures above 1500 oC, Sc15C19 is incompletely formed by subsequent reaction with carbon. The product melts at cca. 1800 oC; carbon dissolves and the final composition approaches ScC2. Carbon separates during solidification. The phase fractionsin the products are affected by evaporation, the vapour pressures above both Sc2OC and Sc15C19 being comparable with the pressure requisite for the carboreduction process. The results are discussed with respect to the often ambiguous published data. (Author)
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