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[en] ESR spectra of anion-radicals of Mo (π-cyclopentadienyl) (nitrosyl) dicarbonyl and of molybdenum (σ-methyl) (π-cyclopentadienyl) tricarbonyl photolysis products are studied. Anion-radicals have the structure of aminyl radicals with localization of unpaired electron on nitrogen atom. Photolysis of cyclopentadienyl methyltricarbonyl molybdenum and its derivatives containing trivalent phosphorus compounds as ligands results in paramagnetic compounds due to oxidation processes
Journal
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya; ISSN 0002-3353; 
; CODEN IASKA; (no.9); p. 2147-2150
; CODEN IASKA; (no.9); p. 2147-2150