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AbstractAbstract
[en] The Te2-pressure over Mo3Te4 and MoTe2 as well as over equilibrium mixtures of Mo+Mo3Te4, Mo3Te4+MoTe2, and MoTe2+Te.l, respectively, has been measured directly between 1100 and 1373 K. No remarkable deviations from stoichiometry exist for MoTe2 as well as for Mo3Te4. The coexistence pressures are for Mo/Mo3Te4: lg p/105 Pa = 5.56-9879/T, and for Mo3Te4/MoTe2: lg p/105 Pa = 8.398-11790/T. Third law enthalpies are derived: Δ/sub f/H0(298, Mo3Te4) = -195.5 +- 10 with S0(298) = 268, and Δ/sub f/H0(298, αMoTe2) = -89.5 +- 11 with S0(298) = 115.3 (values in kJ/mol and J mol-1K-1, respectively). (author)
Original Title
Untersuchungen der Zersetzungsgleichgewichte und zur Phasenbreite der Molybdaentelluride
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Record Type
Journal Article
Journal
Zeitschrift fuer Anorganische und Allgemeine Chemie (1950); ISSN 0044-2313;
; CODEN ZAACA; v. 543 p. 97-103

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