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[en] Constants of molybdenum (5) ion hydrolysis in perchlorate solutions are determined and phase diagram of its oxo- and hydroxo complexes is plotted. It follows from the diagram that MoO2+ cations dominate in a wide range of pH value from pH3 to 2-3 mol/l HClO4. In less acid solutions MoO2OH hydroxo complexes are formed, in more acid solutions - unstable MoO3+ cations frequenty oxidized to molybdenum blue
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