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AbstractAbstract
[en] Ammonia synthesis from H2-N2 mixed gas was studied at room temperature in a glow-discharge plasma in the presence of metals or metal oxides. Magnesia (Mg0) and calcia (CaO), which are oxides with solid basicity, revealed catalytic activity in the plasma synthesis of ammonia, although they are catalytically inactive in industrial ammonia synthesis. The acid oxides (Al203 W03, and Si02-Al203) lead to the consumption of the reactant, i.e., the H2-N2 mixed gas. No ammonia was isolated. Metal catalysts showed higher activity than the above basic oxides. They have, however, different activities. The reaction was faster over the active materials than over sodium chloride (NaCl) or glass wool or in a blank reactor without any catalyst
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ALKALINE EARTH METAL COMPOUNDS, ALUMINIUM COMPOUNDS, CALCIUM COMPOUNDS, CHALCOGENIDES, ELECTRIC DISCHARGES, ELEMENTS, EVALUATION, HYDRIDES, HYDROGEN COMPOUNDS, KINETICS, MAGNESIUM COMPOUNDS, NITROGEN COMPOUNDS, NITROGEN HYDRIDES, NONMETALS, OXIDES, OXYGEN COMPOUNDS, POLAR SOLVENTS, REACTION KINETICS, SILICON COMPOUNDS, SOLVENTS, SPECTROSCOPY, TESTING, TRANSITION ELEMENT COMPOUNDS, TUNGSTEN COMPOUNDS
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