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AbstractAbstract
[en] Exact quantum reaction probabilities for a collinear model of the F + HH, HD, DD and DH reactions on the MV potential energy surface have been computed using hyperspherical coordinates. The results, obtained up to a total energy of 1.8 eV, show three main features: (i) resonances, whose positions and widths are analysed simply in the hyperspherical formalism; (ii) a slowly varying background increasing for FHD, decreasing for FDH, and oscillating for FHH and FDD, whose variations are interpreted by classical dynamics; (iii) partial reaction probabilities revealing decreasing vibrational adiabaticity in the order FHH-FDD-FHD-FDH. (author)
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Source
GRANT NATO 328/82
Record Type
Journal Article
Literature Type
Numerical Data
Journal
Journal of Physics. B, Atomic and Molecular Physics; ISSN 0022-3700;
; CODEN JPAMA; v. 19(18); p. 2779-2792

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