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AbstractAbstract
[en] Peculiarities of es solvated electron optical absorption in liquid non-polar systems, produced in the course of ND3 and N2D4-butanol mixture (1:2) dilution by alkanes, are studied by pulse radiolysis method. It is ascertained, that the medium conduction band bottom position practically does not effect the spectral characteristics of es, which appear to depend on solution concentration. The results are discussed on the basis of light absorption phenomenon semiquantitative analysis under the absence of polar continuum with the participation of representations on the band broadening heterogeneous mechanism and on the change of es photoexcited state nature at varying concentrations
Original Title
Spektral'nye osobennosti sol'vatirovannykh ehelektronov v nepolyarnykh rastvorakh ammiaka i gidrazina
Source
For English translation see the journal High Energy Chemistry (USA).
Record Type
Journal Article
Journal
Country of publication
ALCOHOLS, CHEMICAL RADIATION EFFECTS, CHEMICAL REACTIONS, DECOMPOSITION, DISPERSIONS, ELECTRONS, ELEMENTARY PARTICLES, FERMIONS, HOMOGENEOUS MIXTURES, HYDRIDES, HYDROCARBONS, HYDROGEN COMPOUNDS, HYDROXY COMPOUNDS, IRRADIATION, LEPTONS, MIXTURES, NITROGEN COMPOUNDS, NITROGEN HYDRIDES, OPTICAL PROPERTIES, ORGANIC COMPOUNDS, PHYSICAL PROPERTIES, POLAR SOLVENTS, RADIATION EFFECTS, SOLVENTS, SPECTRA
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