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McClanahan, E.D.; Bradley, E.R.
Pacific Northwest Lab., Richland, WA (USA)1988
Pacific Northwest Lab., Richland, WA (USA)1988
AbstractAbstract
[en] Pacific Northwest Laboratory (PNL) has developed and demonstrated a pilot process for trapping and storing 85Kr recovered and purified from the dissolver off-gas stream of a nuclear fuel reprocessing plant. Ions produced in a low-pressure krypton discharge are implanted in a growing sputtered film of Cu/sub 0.67/Y/sub 0.25/Kr/sub 0.08/ deposited on the inner wall of a krypton trapping storage device (KTSD). A main objective of this work is to measure the release of 85Kr implanted in a copper-yttrium alloy. The overall release characteristics of the deposits are quite favorable for long-term storage. Both the radioactive and nonradioactive test specimens stored at temperatures not exceeding 350/degree/C have shown that the release rates measured to date are <0.1% yr-1. The release rates for the radioactive specimens were obtained for storage periods of 1.6, 1.1 and 0.4 yr for 150, 250 and 350/degree/C storage temperatures, respectively. The nonradioactive specimen has been held at temperatures ranging between 180 and 450/degree/C, but mainly at 350/degree/C, for a total storage time of 2.1 yr. Following the /approximately/10-yr monitoring period, the remaining Cu-Y-85Kr waste form should be evaluated to better predict overall stability for the full storage period (50 to 100 yr). 5 refs., 6 figs., 2 tabs
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Jul 1988; 17 p; 20. DOE/NRC nuclear air cleaning conference; Boston, MA (USA); 22-25 Aug 1988; CONF-880815--1; Available from NTIS, PC A03/MF A01; 1 as DE89000400; Portions of this document are illegible in microfiche products.
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Report
Literature Type
Conference
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ALLOYS, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, CHEMICAL ANALYSIS, CONTAINERS, ELEMENTS, EVEN-ODD NUCLEI, GRAVIMETRIC ANALYSIS, HOURS LIVING RADIOISOTOPES, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, KRYPTON ISOTOPES, MANAGEMENT, NONMETALS, NUCLEAR FACILITIES, NUCLEI, QUANTITATIVE CHEMICAL ANALYSIS, RADIOISOTOPES, RARE GASES, STORAGE, THERMAL ANALYSIS, WASTE MANAGEMENT, WASTE STORAGE, YEARS LIVING RADIOISOTOPES
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