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AbstractAbstract
[en] A study has been made to evaluate lanthanide mobility in sediments directly by measuring concentrations of 10 lanthanide elements in sediments and pore waters. Due to the very low concentrations of the lanthanides in sea water relative to marine sediments, evidence of lanthanide mobilization is usually difficult to detect from studies of solid-phase geochemistry. Results show that the lanthanides can be extremely mobile. Concentrations in pore waters up to 100 times sea water concentrations have been measured. The conclusions are tentative but the present data suggest that the lanthanides are mobilized during oxidation of organic-rich sediments and are relocated in part in association with secondary Fe-rich phases. The behaviour of Ce is, predictably, somewhat different from the other lanthanides and may be more mobile as a consequence of its redox chemistry. (author)
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Jul 1988; 21 p; CONTRACT PECD-7/9/091
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