Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.019 seconds
Saitovitch, E.B.; Scorzelli, R.B.; Azevedo, I.S.; Micklitz, H.
Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro (CBPF), RJ (Brazil)1989
Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro (CBPF), RJ (Brazil)1989
AbstractAbstract
[en] In situ high temperature 57Fe Moessbauer measurements were performed on samples of YBa2(Cu1-xFex3O7-δ, in pure oxygen or in air, both at a pressure of about 1 atm. Three samples were studied with x = 0.005 and 0.010, respectively in the temperature range from 295 to 640 K. As in previously published papers, the fitted quadrupole doublets were associated to different oxygen configurations around the Fe ions on the Cu(1) chain site, whose temperature dependent behavior can be summarized: i) the f-factor for the different configurations are very similar; ii) the effective Debye temperature (≅ 350 k) is rather insensitive to the Fe content and oxygen coordination; iii) the electronic configuration of Fe is very stable up 320 C; iv) the quadrupole splitting q(T) can be well described within the picture use for non cubic metals, Finally a partial change from doublet A to B induced by temperatures is observed. This change is completely or partially reversible, depending on the sample. (author)
[pt]
Medidas Moessbauer do 57Fe a alta temperatura in situ foram feitas sobre amostras de YBa2(Cu1-xFex)3O7-δ, em oxigenio puro ou em ar, ambos a pressao de 1 atm. Tres amostras foram estudadas com x=0.005 e 0,010, respectivamente no intervalo de temperatura de 295 a 640 K. Como em artigos publicados anteriormente. Os doublets de quadrupolo ajustados foram associados a diferentes configuracoes do oxigenio em torno dos ions de Fe sobre a cadeia local de Cu(1), cujo comportamento dependente da temperatura pode ser resumido: i) o fator-f para as diferentes configuracoes sao muito similar; ii) a temperatura efetiva de Debye (≅ 350 K) e menos suscetivel ao conteudo de ferro e coordenacao do oxigenio; iii) a configuracao eletronica do Fe e mais estavel ate 3200C; iv) a divisao do quadrupolo q (T) pode ser bem descrita dentro do quadro usado para metais nao cubicos. Finalmente uma variacao do doublet A para B induzido pela temperatura e observado. Esta variacao e completamente ou parcialmente versivel dependendo da amostra. (M.C.K.)Primary Subject
Source
1989; 26 p
Record Type
Report
Report Number
Country of publication
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue