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Ball, R.G.J.; Rand, M.H.
Netherlands Energy Research Foundation, Petten (Netherlands)1991
Netherlands Energy Research Foundation, Petten (Netherlands)1991
AbstractAbstract
[en] Thermochemical data are required for specific fission product and reactor materials compounds in order to quantify the consequences of a severe accident within a light water reactor. Approximately 40 important compounds/systems have been identified for study for which thermodynamic data did not exist or were inadequate. Work is described on the analysis of approx. half these systems. Experimental studies have been undertaken to compounds: Cs2MoO4(g), CsBO2(g), Cs2RuO4(c), Cs2RuO4(g), Cs2MnO4(c), Cs2CrO4(g), Cs2TeO3(g), Cs2Te(g), InI(g), InI3(g), In2I6(g), In2Te(g), Cd(OH)2(c), Cd(OH)2(g), TeO(OH)2(g), CdI2(g), Cd2I4(g), Cs2CdI4(c), CsCdI3(g), Cs2CdI4(g)Cs3PO4(c) and Cd-In-Ag. Critical assessments have been made on the following systems: In-I, In-Te, Cd-I, Sr-B-O and Ba-B-O. The thermodynamic quantities of these compounds have been calculated over the temperature range from 298 to 3000 K. The adoption of these data within appropriate modelling codes will allow the fission product species and transport to be predicted with greater confidence, thus providing more accurate assessments of the consequences of severe reactor accidents. (author). 69 refs.; 36 figs.; 46 tabs
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Feb 1991; 189 p; CONTRACT NO. 3876-89-12 EL ISP NL; Photo-copies available from Library KNAW; P.O.Box 41950, 1009 DD Amsterdam, The Netherlands; This work was prepared for the Commission of the European Communities.
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