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AbstractAbstract
[en] The reduction of anhydrous bromide, CeBr3, with metallic cerium or lithium results in the formation of black single crystals with a brass lustre. Ce2Br5 crystallizes with the monoclinic crystal system. There are two crystallographically independent sites for cerium in the unit cell that have coordination numbers of seven (Ce1) and eight (Ce2) with mean distances, d(Ce-Br), of 304.5 and 310.2 pm, respectively. Therefore, it is believed that cerium is trivalent and the formula has to be written as (Ce3+)2 (Br-)5 (e-)
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Secondary Subject
Source
Conference on New Developments in f-Elements; Louvain (Belgium); 4-7 Sep 1990
Record Type
Journal Article
Literature Type
Conference
Journal
European Journal of Solid State and Inorganic Chemistry; CODEN EJSCE; v. 28(Suppl.); p. 523-528
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