Photostimulated reactions of outerspheric electron transfer with participation of platinum (4) halogenamine complexes and ruthenium (2) tris-bipyridyl complex

Balashev, K.P.; Zimnyakov, A.M.

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Photostimulated reactions of outerspheric electron transfer with participation of platinum (4) halogenamine complexes and ruthenium (2) tris-bipyridyl complex

Balashev, K.P.; Zimnyakov, A.M.1991

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AbstractAbstract

[en] Kinetics and mechanism of photostimulated bimolecular reactions with participation of [RuBipy₃]²⁺-[Pt(NH₃)_nX_6-n]^z± (n=0-6; X=Cl^-, Br^-) have been studied. The values of bimolecular constants of electron phototransfer initial reaction rate and efficiency of charge separation in the initial ion pair ([Ru(3)]...[Pt(3)]) are obtained

Original Title

Fotostimulirovannye reaktsii vneshnesfernogo perenosa ehlektrona s uchastiem galogenaminovykh kompleksov platiny (4) i tris-bipiridil'nogo kompleksa ruteniya (2)

Primary Subject

INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY (B1210)

Record Type

Journal Article

Journal

Koordinatsionnaya Khimiya; ISSN 0132-344X;

; CODEN KOKHD; v. 17(4); p. 523-529

Country of publication

USSR

Descriptors (DEI)

AMMONIA, BIPYRIDINES, CHEMICAL REACTION KINETICS, ELECTRON TRANSFER, HALIDES, ION PAIRS, LUMINESCENCE, PHOTOCHEMISTRY, PLATINUM COMPLEXES, RUTHENIUM COMPLEXES

Descriptors (DEC)

AZINES, CHEMISTRY, COMPLEXES, EMISSION, HALOGEN COMPOUNDS, HETEROCYCLIC COMPOUNDS, HYDRIDES, HYDROGEN COMPOUNDS, KINETICS, NITROGEN COMPOUNDS, NITROGEN HYDRIDES, ORGANIC COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, PHOTON EMISSION, PYRIDINES, REACTION KINETICS, TRANSITION ELEMENT COMPLEXES

LanguageLanguage

Russian

Reference NumberReference Number

23016064

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