Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.014 seconds
AbstractAbstract
[en] The adsorption of 85Sr2+ on bitumen emulsions with well characterized surfaces was studied as function of pH and ionic strength of the equilibrium solution. The bitumen/solution interface is negatively charged due to the deprotonation of weakly acidic carboxyl groups present at the surface. The surface group density is calculated to be 1.37x1018 groups/m2 and the deprotonation behaviour can be fairly well described by the Ionizable Surface Group Model with a pKH = 6.6. Sr2+ adsorbs on the bitumen by an outer sphere complexation reaction in which one surface carboxyl group is involved in the adsorption of one Sr2+-ion. The adsorption depends on the ionic strength and pH of the contact solution. The higher the ionic strength, the lower the adsorption. Sorption increases with increasing pH due to the deprotonation of carboxyl groups. In a cementitious environment, Sr2+ adsorption on bitumen is negligible due to the strong competition of Na+, K+ and Ca2+ present in the cement pore water. (orig.)
Secondary Subject
Record Type
Journal Article
Journal
Country of publication
ALKALINE EARTH METAL COMPOUNDS, BETA DECAY RADIOISOTOPES, CHEMICAL REACTIONS, DAYS LIVING RADIOISOTOPES, ELECTRON CAPTURE RADIOISOTOPES, EVEN-ODD NUCLEI, HOURS LIVING RADIOISOTOPES, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MANAGEMENT, NUCLEI, ORGANIC COMPOUNDS, OTHER ORGANIC COMPOUNDS, RADIOISOTOPES, SEPARATION PROCESSES, STRONTIUM ISOTOPES, TAR, WASTE MANAGEMENT, WASTE PROCESSING
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue