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AbstractAbstract
[en] The kinetics of electron capture by CH3Br was investigated using the electron swarm method. Carbon dioxide and ethylene were used as carrier gases. The rate constant obtained for thermal electron attachment is equal (in both carrier gases) to (5.3±0.1) x 10-12cm3 molecule-1 s-1. The electron attachment mechanism and kinetics in the mixture containing CH3Br and H2S with CO2 as a carrier gas were also investigated. The rate of this process was found to be formally of the fourth order. The mechanism involving van der Waals complexes (CH3Br·H2S) is proposed. The rate constants for the process as well as the lifetime of the complex negative ion were calculated. (author)
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GRANT CPBP 01.19
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Journal Article
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CAPTURE, CHALCOGENIDES, CHEMICAL RADIATION EFFECTS, CHEMICAL REACTIONS, DECOMPOSITION, ELECTROMAGNETIC RADIATION, HYDROGEN COMPOUNDS, IONIZING RADIATIONS, KINETICS, ORGANIC BROMINE COMPOUNDS, ORGANIC COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, RADIATION EFFECTS, RADIATIONS, REACTION KINETICS, SULFIDES, SULFUR COMPOUNDS
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