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Godon, N.; Vernaz, E.; Gin, S.; Beaufort, D.; Thomassin, J.H.
CEA Centre d'Etudes de la Vallee du Rhone, 30 - Marcoule (France). Dept. des Procedes de Retraitement1991
CEA Centre d'Etudes de la Vallee du Rhone, 30 - Marcoule (France). Dept. des Procedes de Retraitement1991
AbstractAbstract
[en] Static experiments have been developed to investigate the R7T7 glass corrosion in four natural salt brines (brines 1 and 3: pure halite, brines 2 and 4: high Mg, K fluid inclusions rich halite), at 90 deg C and 150 deg C with 0.7 cm-1 S/V ratio and at 11 different running times. Analysis of brines after alteration (pHmeter and ICP) added to a detailed study of the crystalline phases developed at the interface glass-brine (XRD,SEM and Microprobe), showed that the influence of the compositional difference is more important on the nature of the secondary phases formed than on the corrosion rate of the glass. After 91 days of alteration at 150 deg C stady states to be reached (after 40 days at 90 deg C). A long term experiment (1 year) is necessary to confirm this hypothesis. 7 refs., 7 figs., 2 tabs
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1991; 15 p; 15. International Symposium on the Scientific basis for Nuclear Waste Management; Strasbourg (France); 4-7 Nov 1991
Record Type
Report
Literature Type
Conference; Numerical Data
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BOROSILICATE GLASS, BRINES, CHEMICAL ANALYSIS, CORROSION RESISTANCE, EMISSION SPECTROSCOPY, EXPERIMENTAL DATA, LEACHATES, LEACHING, MICROANALYSIS, MONTMORILLONITE, RADIOACTIVE WASTE DISPOSAL, SALTS, SCANNING ELECTRON MICROSCOPY, SMECTITE, TEMPERATURE RANGE 0273-0400 K, TEMPERATURE RANGE 0400-1000 K, TIME DEPENDENCE, X-RAY SPECTROSCOPY, ZEOLITES
CLAYS, DATA, DISPERSIONS, DISSOLUTION, ELECTRON MICROSCOPY, GLASS, HOMOGENEOUS MIXTURES, INFORMATION, INORGANIC ION EXCHANGERS, ION EXCHANGE MATERIALS, MANAGEMENT, MATERIALS, MICROSCOPY, MINERALS, MIXTURES, NUMERICAL DATA, SEPARATION PROCESSES, SILICATE MINERALS, SOLUTIONS, SPECTROSCOPY, TEMPERATURE RANGE, WASTE DISPOSAL, WASTE MANAGEMENT
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