[en] The Canadian Fusion Fuels Technology Project is evaluating the uptake and release of tritium (DT, T₂), tritiated hydrogen (HT) and tritiated water (HTO) by building materials to be used in fusion reactor enclosures. Concrete will be an important building material and poses a special problem because of its porous microstructure and the chemical makeup of the material. One approach to reducing the uptake of HT and HTO into concrete is to apply a permeation barrier directly onto the concrete. Glazed ceramic tiles are one barrier with low HT and HTO uptake; however, the grouting between tiles is a major concern. It would be desirable to seal the grout with a glassy permeation barrier. The concept investigated in this program is based on plasma spraying: injecting a powder into a high velocity flame to melt the powder particles and project them towards a target substrate. Glass on the substrate is then to be fused by the plasma flame while a molten glass is deposited on top. Ceramic bonded grouts were developed based on fused silica or borosilicate powders and ethyl silicate or sodium silicate air-set binders. Sodium silicate grouts exhibit lower porosity after drying than ethyl silicate-based grouts, although both are porous. Careful control of the ratio of coarse to fine powder fractions is necessary to minimize or eliminate drying shrinkage. The surface of grouts based on borosilicate glass could not be fused without cracking of neighbouring tiles. When a porcelain enamel glass was plasma spray deposited and fused onto the surface of a grout line and adjacent tiles crazing was observed upon dye penetrant testing