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AbstractAbstract
[en] Partially stabilized zirconia was vacuum furnace brazed to itself, to nodular cast iron, and to commercially pure titanium with a Ag-30Cu-10Sn wt% filler metal. Wetting was obtained by coating the ZrO2 surfaces with Ti prior to brazing by RF sputtering or electron beam evaporation. Braze joints made with Ti-sputter-coated ZrO2 contained high levels of porosity, but those made with Ti coatings deposited by evaporation, referred to as Ti-vapor-coated, contained little or no porosity. Brazing caused the ZrO2 within about 1 mm (0.04 in.) of the joint surfaces to turn black in color, and thermodynamic analysis indicated that the discoloration was likely due to oxygen diffusion out of the ZrO2 into the Ti vapor coating during brazing. Braze joint strength was determined by flexure testing in the four-point bend arrangement, and on a more limited basis, by shear testing. The latter method was used mainly as a screening test for ZrO2-Fe and ZrO2-Ti joints. Flexure testing of ZrO2-ZrO2 and ZrO2-Fe braze joints was done at 25, 200, 400, and 575 C (77, 392, 752 and 1,067 F) in air. For flexure testing, average strengths of joint specimens decreased with increasing test temperature. The lower average strengths of ZrO2-Fe specimens compared to those from ZrO2-ZrO2 joints was attributed to higher residual stresses in the ceramic-to-metal joints
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