Thermodynamic and formation kinetics of heterovalent tartrate complexes of iron (2,3) and vanadium (3,4) in aqueous solutions

Glebov, A.N.; Budanov, A.R.

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Thermodynamic and formation kinetics of heterovalent tartrate complexes of iron (2,3) and vanadium (3,4) in aqueous solutions

Glebov, A.N.; Budanov, A.R.1992

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AbstractAbstract

[en] Kinetics of heterovalent tartrate complexes (HVC) in the systems Fe(2) - Fe(3) and V(3) - V(4) was studied by the method of stopped jet with optical recording. A mechanism of HVC formation, involving two reversible stages, was suggested. By computer simulation rate constants of separate stages were found. Thermodynamic and kinetic parameters are compared

Original Title

Termodinamika i kinetika obrazovaniya geterovalentnykh tartratnykh kompleksov zheleza (2,3) i vanadiya (3,4) v vodnykh rastvorakh

Primary Subject

INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY (B1210)

Record Type

Journal Article

Journal

Koordinatsionnaya Khimiya; ISSN 0132-344X;

; CODEN KOKHDC; v. 18(9); p. 964-967

Country of publication

Russian Federation

Descriptors (DEI)

AQUEOUS SOLUTIONS, CHEMICAL PREPARATION, CHEMICAL REACTION KINETICS, STABILITY, TARTRATES, THERMODYNAMIC PROPERTIES, VANADIUM COMPLEXES

Descriptors (DEC)

CARBOXYLIC ACID SALTS, COMPLEXES, DISPERSIONS, HOMOGENEOUS MIXTURES, KINETICS, MIXTURES, PHYSICAL PROPERTIES, REACTION KINETICS, SOLUTIONS, SYNTHESIS, TRANSITION ELEMENT COMPLEXES

LanguageLanguage

Russian

Reference NumberReference Number

24065874

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