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Prabhutendulkar, A.N.; Ravindran, P.V.; Radhakrishnan, T.P.
Proceedings [of the] symposium on zirconium alloys for reactor components1992
Proceedings [of the] symposium on zirconium alloys for reactor components1992
AbstractAbstract
[en] Oxidation and hydrogen uptake of zircaloy-2, pretreated under various conditions, were studied in steam at atmospheric pressure in the temperature range of 1016-1170 k. A comparative study of the oxidation of cold-rolled and alpha-annealed specimens of zircaloy-2 under these conditions indicated that oxidation proceeded in accordance with a cubic rate law. The activation energy and pre exponential factor for the oxidation of alpha-annealed zircaloy-2, viz., 34.8 Kcal.mole-1 and 2.1 x 1012 mg3 dm-6.min-1, respectively, were significantly lower than those for cold-rolled zircaloy-2 (E=47.2 Kcal.mole-1 and A=3.3 x 1014mg3.dm-6.min-1). The breakaway oxidation of cold-rolled zircaloy-2 at 1016 K under these conditions was initiated after 331 minutes when the oxide layer was 13μm thick. In contrast, exposure of alpha-annealed zircaloy-2 to steam at 1016 K for upto 456 minutes produced an oxide layer of about 20 μm thickness, without exhibiting any significant breakaway oxidation during this period. The breakaway oxidation of cold-rolled zircaloy-2 could be significantly delayed by surface modification effected by anodisation of the specimen at a current density of 9 mA cm-2 for 30 minutes in sodium nitrate melt. In these cases, the onset of breakaway transition at 1016 K was observed only after 615 minutes although the corresponding thickness of the oxide layer was only 22μm. The hydrogen uptake during steam oxidation of cold-rolled zircaloy-2 followed a cubic rate law, whereas that for alpha-annealed zircaloy-2 showed a parabolic dependence on time. The hydrogen uptake of alpha-annealed zircaloy-2 specimens anodised in sodium nitrate melt for 30 minutes at a current density of 1.4 mA.cm-2 was significantly lower (903 ppm in 7 h at 1016 K) than that for uncoated alpha-annealed specimens (1200 ppm in 8 h at 1016 K). Further, the hydrogen uptake values showed a parabolic dependence on the oxygen weight gain of the specimen. (author). 5 refs., 8 figs., 2 tabs
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Department of Atomic Energy, Bombay (India). Board of Research in Nuclear Sciences; 738 p; 1992; p. 598-618; Bhabha Atomic Research Centre; Bombay (India); ZARC-91: symposium on zirconium alloys for reactor components; Bombay (India); 12-13 Dec 1991
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Book
Literature Type
Conference
Country of publication
ALKALI METAL COMPOUNDS, ALLOYS, CHEMICAL REACTIONS, CHROMIUM ADDITIONS, CORROSION RESISTANT ALLOYS, ELEMENTS, FABRICATION, HEAT RESISTING ALLOYS, HEAT TREATMENTS, IRON ADDITIONS, KINETICS, MATERIALS WORKING, NICKEL ADDITIONS, NITRATES, NITROGEN COMPOUNDS, NONMETALS, OXYGEN COMPOUNDS, REACTION KINETICS, SODIUM COMPOUNDS, TEMPERATURE RANGE, TIN ALLOYS, ZIRCALOY, ZIRCONIUM ALLOYS, ZIRCONIUM BASE ALLOYS
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