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AbstractAbstract
[en] Magnetic susceptibility measurements show an antiferromagnetic ordering phenomenon for K2UBr5. There is a broad maximum in the χ versus T curve at about 10 K. Aiming at the determination of the magnetic structure of K2UBr5, powder neutron diffraction investigations were performed. The nuclear structure of K2UBr5(K2PrCl5 type of structure) was refined at 15 K in the paramagnetic state. The magnetic structure, which was determined from a measurement at 1.5 K in the magnetically ordered state, belongs to the Shubnikov space group Pn'm'a' with k = 0. In the uranium chains along [010] there is an antiferromagnetic ordering of the magnetic moments with components in the (010) plane only. The magnetic moments of neighboring chains are perpendicular to each other within the error limit. Each U3+ has an ordered magnetic moment of 2.31(4) μB. According to the temperature dependence of the intensity of the 010 and 111 magnetic peaks the Neel temperature is 2.8(3) K. Presumably, there is a short-range magnetic ordering along the [UBr3Br4/2]2- chains giving rise to the maximum of χ at T = 10 K, followed by long-range (three-dimensional) ordering at 2.8 K. 19 refs., 5 figs., 3 tabs
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CRYSTAL STRUCTURE, MAGNETIC MOMENTS, MAGNETIC SUSCEPTIBILITY, MILLER INDICES, NEEL TEMPERATURE, NEUTRON DIFFRACTION, NUCLEAR STRUCTURE, PEAKS, POTASSIUM COMPOUNDS, TEMPERATURE DEPENDENCE, TEMPERATURE RANGE 0000-0013 K, TEMPERATURE RANGE 0013-0065 K, TEMPERATURE RANGE 0065-0273 K, TEMPERATURE RANGE 0273-0400 K, URANIUM BROMIDES
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