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Whitlow, G.A.; Lovic, W.R.
Westinghouse Electric Corp., Pittsburgh, PA (United States)1993
Westinghouse Electric Corp., Pittsburgh, PA (United States)1993
AbstractAbstract
[en] A method of producing a high temperature ceramic superconductor is described comprising the steps of: providing core pellets of pressed particles of metal oxides selected from the group consisting of Bi.Sr.Ca.Cu.O and Bi.Pb.Sr.Ca.Cu.O, placing the pellets within a metallic sheath, thereby forming a sheath-pellet structure, reducing the cross-section of the sheath-pellet structure, thereby providing a composite comprising said metallic sheath and a ceramic oxide core, and heat treating the composite, sealing the composite in a container assembly, having a high temperature resistant compression/separation medium containing 40% to 95% of a porous material selected from the group consisting of particulate material and fibrous material, and a thin metal outer portion surrounding the metallic sheath, under vacuum conditions, thereby placing the core under vacuum to ease compression thereof, and then hot isostatically pressing the composite through the compression/separation medium at from 352 kg/cm2 to 3,172 kg/cm2, and at a temperature over 600 C. thereby initiating melting of the ceramic oxide core but not of the metallic sheath while causing plastic flow of said metallic sheath, and thereby causing from 1% to 20% reduction in the cross-section of the composite and intimate contact between the core and the sheath at their interface while compressing said core to near its theoretical density and thus eliminating voids therein, and then, composite and compression/separation medium, and then annealing the composite in a source of oxygen, at a temperature from 770 C to 870 C for 40 hours to 200 hours, thereby maximizing current density of the core
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Source
29 Jun 1993; 30 May 1991; [10 p.]; US PATENT DOCUMENT 5,223,478/A/; Patent and Trademark Office, Box 9, Washington, DC 20232 (United States); ?: 30 May 1991
Record Type
Patent
Country of publication
ALKALINE EARTH METAL COMPOUNDS, BISMUTH COMPOUNDS, CALCIUM COMPOUNDS, CHALCOGENIDES, COPPER COMPOUNDS, ELECTRIC CONDUCTIVITY, ELECTRICAL PROPERTIES, LEAD COMPOUNDS, MATERIALS WORKING, OXIDES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, PRESSING, STRONTIUM COMPOUNDS, SUPERCONDUCTORS, TRANSITION ELEMENT COMPOUNDS
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