Interaction of cyclopentadienylcobalttetraphenylbutadiene with iodine in the presence of electron ligands

Shirokij, V.L.; Knizhnikov, V.A.; Mosin, A.V.; Nefedov, S.E.; Eremenko, I.L.; Yanovskij, A.I.; Struchkov, Yu.T.; Majer, N.A.

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Interaction of cyclopentadienylcobalttetraphenylbutadiene with iodine in the presence of electron ligands

Shirokij, V.L.; Knizhnikov, V.A.; Mosin, A.V.; Nefedov, S.E.; Eremenko, I.L.; Yanovskij, A.I.; Struchkov, Yu.T.; Majer, N.A.1993

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AbstractAbstract

[en] Interaction of η⁵-cyclopentadienylcobalt-η-tetraphenylbutadiene (1) with iodine in the presence of electron-donor ligands -pyridine, dimethylsulfide, 2,2'-dipyridyl (Dipy), 1,10-phenanthroline (Phen) was studied. The interaction of 1 with iodine in the presence of Dipy or Phen leads to the ionic complexes [C₅H₅CoIL]⁺I₃^-, where L = Phen, Dipy. The structure of the latter is established by X-ray analysis

Original Title

Vzaimodejstvie tsiklopentadienilkobal'ttetrafenilbutadiena s iodom v prisustvii ehlektrodonornykh ligandov

Primary Subject

INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY (B1210)

Record Type

Journal Article

Journal

Metalloorganicheskaya Khimiya; ISSN 0235-0114;

; CODEN MEKHEX; v. 6(1); p. 22-25

Country of publication

Russian Federation

Descriptors (DEI)

BIPYRIDINES, CHEMICAL REACTIONS, COBALT, IODINE, LIGANDS, ORGANIC SULFUR COMPOUNDS, PHENANTHROLINE-ORTHO, PYRIDINES

Descriptors (DEC)

AZINES, ELEMENTS, HALOGENS, HETEROCYCLIC COMPOUNDS, METALS, NONMETALS, ORGANIC COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, PHENANTHROLINES, REAGENTS, TRANSITION ELEMENTS

LanguageLanguage

Russian

Reference NumberReference Number

24074122

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