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AbstractAbstract
[en] The rate coefficients for mixing between He(2 3PJ,MJ) levels during collisions with ground-state helium atoms and for conversion of He(2 3PJ) atoms to He2(b 3Πg) molecules via three-body reactions in helium gas have been investigated over the temperature range 1.6--300 K. The measured rate coefficients for collisionally induced P-state mixing decrease slowly with decreasing temperature, from (1.8±0.5)x10-9 cm3 s-1 at 300 K to (4.5±0.5)x10-10 cm3 s-1 at 4.2 K. The rate coefficients for the production of He2(b 3Πg) molecules via three-body reactions are observed to increase with decreasing temperature and are described by the relation kP congruent(2.5+267T-1)x10-32 cm6 s-1. This behavior, which is very different from that noted in earlier studies of the conversion of He(2 3S1) atoms to He2(a 3Σu+) molecules through three-body reactions, suggests that the reaction is not thermally activated
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