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AbstractAbstract
[en] Within the homogeneous range of uranium monocarbide UB1-xC1+x, the crystal structures of stoichiometric UBC and of the carbon-rich solid solution UB0.78C1.22 have been refined from single-crystal X-ray counter data. From X-ray analysis crystal symmetry in both cases is consistent with the centrosymmetric space group Cmcm and there are no indications of superstructure formation. In contrast to the fully ordered atom arrangement revealed for stoichiometric UBC, random occupation by boron and carbon atoms is observed for the boron site in UB0.78C1.22. Neutron powder diffraction experiments at 9 and 295 K unambiguously revealed full occupancy by the nonmetal atoms in UB0.78C1.22 and prove the statistical occupation of B and C atoms in the B-sites. The boron-boron chain in Cmcm (B-B = 0.1874 nm) is dissolved into boron pairs (B-B = 0.1706 nm). The formation of C-B-B-C groups corresponds to the structure types of ThBC and Th3B2C3. The magnetic behavior has been investigated in the temperature range from 4.2 K to 1000 K for UB1-xC1+x (UBC-type) and U1-xMxB2C (ThB2C-type for the high temperature modification and 1-UB2C-type for the low temperature modification) with U partially substituted by Th or Sc, Lu. From magnetic susceptibilities, the alloys UB1-xC1+x reveal temperature independent paramagnetism with typical intermediate valence fluctuation behavior (TSF ∼ 350 K). ThB2C and 1-UB2C both are temperature independent paramagnets, whereas h-UB2C is a ferromagnet with the rather high Curie temperature TM = 80(2) K. TM and the saturation magnetization per U atom both successively decrease on substitution of U by Th, Sc, or Lu in UB2C, whereas the U-moments remain practically unchanged at μeff(U) ∼ 1.9 μB. 20 refs., 8 figs., 5 tabs
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CRYSTAL STRUCTURE, FERROMAGNETIC MATERIALS, LUTETIUM BORIDES, LUTETIUM CARBIDES, MAGNETIC PROPERTIES, MONOCLINIC LATTICES, NEUTRON DIFFRACTION, ORTHORHOMBIC LATTICES, PARAMAGNETISM, SCANDIUM BORIDES, SCANDIUM CARBIDES, TEMPERATURE DEPENDENCE, TEMPERATURE RANGE 0000-0013 K, TEMPERATURE RANGE 0065-0273 K, TEMPERATURE RANGE 0273-0400 K, TEMPERATURE RANGE 0400-1000 K, THORIUM BORIDES, THORIUM CARBIDES, URANIUM BORIDES, URANIUM CARBIDES
ACTINIDE COMPOUNDS, BORIDES, BORON COMPOUNDS, CARBIDES, CARBON COMPOUNDS, COHERENT SCATTERING, CRYSTAL LATTICES, DIFFRACTION, LUTETIUM COMPOUNDS, MAGNETIC MATERIALS, MAGNETISM, MATERIALS, PHYSICAL PROPERTIES, RARE EARTH COMPOUNDS, SCANDIUM COMPOUNDS, SCATTERING, TEMPERATURE RANGE, THORIUM COMPOUNDS, TRANSITION ELEMENT COMPOUNDS, URANIUM COMPOUNDS
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